The experiment consist of two parts :the first one research nucleophilic addition of m-dinitrobenzene, nucleophilic reagent is benzyl cyanide;
实验为两部
:第一部
研究了间二硝基苯
加成反应,
试剂为苄基腈;
The experiment consist of two parts :the first one research nucleophilic addition of m-dinitrobenzene, nucleophilic reagent is benzyl cyanide;
实验为两部
:第一部
研究了间二硝基苯
加成反应,
试剂为苄基腈;
General approaches involve the nucleophilic cycloalkylation, carbenoids addition of certain amino acid derivatives and derivatization from simple cyclopropane compounds.
制备方法包括对简单氨基酸衍生物烷基化、类卡宾加成以及简单
丙烷化合物
衍生化合成等。
By nucleophilic addition and reductive cyclization reaction of the three intermediates, respectively, some azo-heterocyclic derivatives containing a rosinyl skeleton were obtained.
该3个中间体过
取代、还原关
反应后,得到了一些脱氢松香酸甲酯含氮杂
衍生物;
Based on these results and the ESI-MS data, the mechanism of sulfoxidation was proposed to be intramolecular nucleophilic oxygen transfer to a coordinated sulfide.
基于这些结果和电喷雾质谱(ESI-MS)数据,亚砜化反应机理推测为
子内
氧转移到络合
硫醚底物上。
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